State of a System
A set of values of the system variables...
In its broadest sense the state of a
is the information required to reproduce that system as it exists in that instant.
The set of numbers defining the state of a system, for systems made of large
is the position and momentum of all the moving parts at the same instant. Applying the laws of Nature to this initial state, allows us to calculate a future
state. The accuracy of this prediction of the future depends on the precision with which the initial state was known and the precision of our calculations. For some systems the sensitivity to the initial state is so severe that it is not possible to calculate a future state with any useful accuracy even over a short time. These systems are called chaotic.
Consider a system consisting of a simple pendulum with friction so small as to be negligible. It has one moving part, constrained to move in a fixed path. It is possible to predict its motion far into the future if we only know its starting position and velocity.
Now consider a lottery machine system consisting of 40 numbered ping-pong balls in a box with air swirling through it. Such a system is chaotic so that useful predictions of its future state is not possible. We can confidently predict that when the gate is opened some ball will shortly find its way up the spout and leave the chamber.
Next consider a box filled with 1023 nitrogen molecules banging into each other and the walls of the container. In this case we can only predict that the molecules will be pretty equally distributed throughout the box. Both of lottery machine and box of nitrogen predictions are manifestations of the
second law of thermodynamics. The second law just expresses the fact that of all possible future states, the one that occurs is usually the one that is most probable.
Macrostates and Microstates
Let's take a closer look at our box full of nitrogen molecules. The set of numbers identifying the position and momentum of each and every molecule in the box at a particular time is actually a microstate of the system. If I move a single molecule to another location or alter its momentum the new set of numbers is another microstate. With so many molecules and so much random motion among them we may consider every possible microstate equally probable, including the microstates where all the molecules reside in one half of the container.
Why then do we not observe all the molecules in one half of the container for however brief a period of time? Here we need to introduce the notion of a macrostate. Macrostates are collections of microstates that are indistinguishable from one another. If I take two molecules and swap their positions and momenta, since all the molecules are identical the two microstates must be in the same macrostate.
The situation where all the gas is in one half of the container is a macrostate with a huge number of microstates in it. The situation where the gas is uniformly distributed throughout the container is a macrostate with enormously more microstates in it. With all microstates being equally likely, the probability of the occurrence of a particular macrostate is equal to its number of microstates divided by the total number of possible microstates. That makes the probability of the half empty container macrostate so close to zero that the difference may be neglected.
Quantum Mechanical States
is the branch of physics that deals with very small (atom sized) objects and their interactions. The rules of quantum mechanics extend to visible objects as well but the resulting departure from the classical laws of physics, going back to Isaac Newton, is so small as to not be noticeable. Even though not noticeable, for our purposes in considering the nature of
we should be aware that at the quantum mechanical rules apply.